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In this study, the Mo cluster-MoS2 composite was artistically synthesized through a one-step sulfurization process via H2/H2S gas circulation. The Mo6 cluster iodides (MIs) covered in the fluorine-doped tin oxide (FTO) cup substrate through the electrophoretic deposition method (i.e., MI@FTO) were used as a precursor to form a thin-film nanocomposite. Investigations in to the construction, reaction apparatus, and NH3 gas sensing performance were completed in detail. The outcome su