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It is indicated by ratio of iron ions contributions in B sites (octahedral) and A sites (tetrahedral) in magnetite spinel structure, which is much lower than 2.0 (theoretical value for stoichiometric magnetite). The characteristic feature of TMPs collected from the vicinity of old metallurgical plants (180 years) was the high contribution of surface components probably related to the surface oxidation/maghemitization. We found that, TMPs can be easily differentiated from geogenic magnetite based on their magnetic parameters. The TMP