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Future society will need more energy storage than what the current technology can deliver and also need more efficient approaches to mitigate CO2 emission and its consequent climate change. Here we report a new concept of sodium-phenanthrenequinone (Na-PQ) battery that can capture CO2 to heighten its load voltage and specific energy upon discharge and reversibly release CO2 on recharge. A mechanistic study, combining spectroelectrochemistry and theoretical calculation, reveals that CO2 is involved in the discharge reaction by bonding to