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To prevent these undesirable Mn reactions with the electrolyte, a 5 nm TiO2protection layer is applied onto the MnSn2electrode surface via atomic layer deposition. The TiO2-coated MnSn2electrodes do not exhibit the activation overpotential peak. The protection layer also increases the capacity to 612 mAh g-1after 100 cycles at a C/10 current rate with a Coulombic efficiency 99%. This higher capacity is achieved by suppressing the parasitic reaction of Mn with the electrolyte, as is supported by x-ray photoelectron spectroscopy analysis.IL-6 is r