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Mechanism studies indicate that the 3D ordered macropores in the NC matrix are beneficial to the transfer of photogenerated carriers. Furthermore, the highly dispersed CdS QDs on the NC skeleton are able to significantly promote the adsorption of both CO2 and amine molecules and depress the CO2 activation energy barriers by stabilizing the *COOH intermediate, directly contributing to the high activity.The oxygen-dependent nature and limited penetration capacity of visible light render the low efficiency of photodynamic therapy in hypox