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For example, the self-assembly of Mn(ii), tpbn and H2L1 in DMF/EtOH/water affords a mixture of products (1 and 1a) while changing the solvent combination to EtOH/water results in the generation of a single isomer (1a) in a highly selective manner. On the other hand, for the Mn(ii)-tphxn system, different structural isomers have been isolated by varying the dicarboxylates, H2L1 and H2L2 (2vs.5). Similarly, for the Mn(ii)-H2L2 system, a variation in the spacer chain length of bis(tridentate) ligands, tpbn and tphxn resulted in the formatio