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Statistical modeling of calculated reaction coordinates had been utilized while the experimental information reproduced just by assuming an intersystem crossing to yield surface state CoO+ occurring competitively utilizing the spin-allowed development of excited condition CoO+.Calix[6]arenes bearing adamantyl groups at the exo-rim kind pseudorotaxanes with dialkylammonium axles paired to your weakly coordinating [B(ArF)4]- anion. The exo-adamantyl groups give rise to an even more efficient threading with