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The key step for Cl(-I) removal was identified as the formation of ·Cl or ·Cl2- from the oxidation of Cl(-I) by ·SO4- and ·OH, and their contribution ratios were estimated to be 67.4% and 32.6%, respectively.Gold is one of the potential toxic heavy metals. In the present study, Au3+ was detected and removed by newly-designed fluorescent microspheres (MF-CDs), i.e. melamine formaldehyde microspheres incorporated with N and S co-doped carbon dots (N,S-CDs). N,S-CDs played the role as sensing unites and melamine formaldehyde microspheres (