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We find that for all combinations of overlayer and substrate, the charge transfer per bond can be captured by the universal descriptor $\mathcalD = \Delta \chi/\Delta \mathcalR$, where $\Delta \chi$ and $\Delta \mathcalR$ are, respectively, the differences in electronegativity and atomic size between phosphorus and the substrate metal.The development of powerful terahertz (THz) emitters is the cornerstone for future THz applications, such as communication, medical biology, non-destructive inspection, and scientific research. Here, we re