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The management of black water depends primarily on the knowledge of the dynamics of organic matter (OM), iron (Fe), sulfide (S), and manganese (Mn), at the water-sediment boundary (WS. However, the mechanistic path of these substances leading to black water remains unsettled. In this study, a 35-day field study was conducted using the thin-film diffusion gradient technology (DGT) and the planar optrode to address the unknown combined effects of Fe, Mn, OM, S, and tannins from Eucalyptus species on Tianbao reservoir.Our results indicat