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The molecular recognition behavior of the spiroborate cages was evaluated using tris(pyridinium)triazines as tricationic aromatic guests. 1H NMR measurement implied that a discrete 1 1 host-guest complex was formed when 1 equiv. of guest was added to the cage, whereas infinite one-dimensional aromatic stacks were constructed by the addition of 2 equiv. of guest.Designing low-cost and high-performance bifunctional electrocatalysts towards hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is vitally important for wat