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This work provides insight into the interaction of PEDOTPSS/cellulose that will aid in the design of sustainable electronic devices.While green bioplastic based on carbohydrate polymers have showed considerable promise, the methods typically used to prepare them in a single material have remained a significant challenge. In this study, a simple approach is proposed to fabricate high performance cellulose films composed of chemically and physically dual-crosslinked 2,2,6,6-tetramethylpiperidine-1-oxy-oxidized cellulose nanofibers (DC TEM