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Based on the abnormal increase in antistokes peaks of Mn4+ with temperatures, Mg3Eu2Ge3O12Mn4+ phosphor also presents a potential application in optical thermometry sensors. This work initiates a new insight to construct thermally stable and spectra-tunable red phosphors for various optical applications. © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH Co. KGaA, Weinheim.Electronics allowing for visible light to pass through are attractive, where a key challenge is to make the core functional units transparent. Here, it is