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5% and a water evaporation rate of 1.669 kg m-2 h-1 under 1 sun irradiation. The present work would provide new insights for the increase in the efficiency of photothermal materials.Two kinds of dumbbell-shaped acceptor-donor-acceptor (A-D-A)-type triad single-component (SC) photovoltaic molecules based on a benzodithiophene-rhodanine (BDTRh) core and [6,6]-phenyl-C61 butyric acid (PC61BA) termini, BDTRh-C2-PC61BA and BDTRh-C10-PC61BA, were synthesized by modulating the alkyl (C2 and C1 spacer lengths. Both SC photovoltaic structures