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5-5 μm). The proposed design concepts are applicable from near-infrared to Terahertz regions via structural engineering.Vanadium pentoxide (V2O5) possesses great potential for application as cathode materials for aqueous zinc-ion batteries due to abundant valences of vanadium. Unfortunately, the inferior electronic conductivity and confined interlayer spacing of pristine V2O5 are not able to support fast Zn2+ diffusion kinetics, leading to significant capacity degradation, the dissolution of active species, and unsatisfactory cycling life. Herein,