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These results demonstrate the structural superiority of the nanoconfined structure and provide valuable information for the rational design and construction of Sb-based anode materials for high-performance electrochemical energy storage.Radiotherapy (RT) in practical use often suffers from off-target side effects and ineffectiveness against hypoxic tumor microenvironment (TME) as well as remote metastases. With regard to these problems, herein, we provide semiconductor heterojunction structured WO2.9-WSe2-PEG nanoparticles