https://www.selleckchem.com/pr....oducts/pyrrolidinedi
We propose that loss of chelated ligands proceeds via C-O scission for highly electronegative transition metals but M-O scission for transition metals with low electronegativity. These results establish 2D-COS as a powerful tool to deconvolute and correlate individual components, enabling mechanistic analysis of complex chemical reactions.The traditional end-to-end cyclization of long-chain linear precursors is difficult and often unpredictable because the unfavorable entropy of macrocyclic closure al