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The creation of efficient artificial systems that mimic natural photosynthesis represents a key current challenge. Here, we describe a high-performance recyclable photocatalytic core-shell nanofibre system that integrates a cobalt catalyst and a photosensitizer in close proximity for hydrogen production from water using visible light. The composition, microstructure and dimensions-and thereby the catalytic activity-of the nanofibres were controlled through living crystallization-driven self-assembly. In this seeded growth strategy, block