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Heterogeneous reactions at the mineral-water interface are of paramount importance in controlling the transport of contaminants. Herein, antimony (Sb) adsorption and subsequent precipitation on Fe2O3 facets were explored to understand its partitioning mechanisms by multiple complementary techniques. Our extended X-ray absorption fine structure spectroscopy and density functional theory results provided a consensus on the local coordination environment of Sb(III) and Sb(V) on Fe2O3 facets. We observed that Sb adsorption and the following
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