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65 V versus Ag/AgCl, which is ∼2.5-folds higher than that of the WOF (without Au loading), as well as very high stability, and no NH3 formation was found for the bare W18O49 (WO). This high activity can be associated with the synergistic effects between the Fe dopant and plasmonic Au NPs on the host semiconductor W18O49. This work can bring some insights into the target-directed design of efficient plasmonic hybrid systems for N2 fixation and artificial photocatalysis.Malaria is an infectious disease caused by Plasmodium parasites, tra