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The adsorption mechanism was that the Pb(II) reacted with the S atoms on surface of MoS2@Kaolin under oxidation conditions provided by molybdenum disulfide to form the insoluble compound β-Pb3O2SO4 in aqueous solution. MoS2@Kaolin was an adsorbent for Pb(II) in aqueous solution with excellent adsorption properties and application potential.Aimed to achieve "waste control by waste" of coal-to-liquids (CTL) industry, coal gasification residue (CGR), the most typical CTL residue, and coal chemical wastewater (CCW) were used as aluminosilica